[Bis(trifluoroacetoxy)iodo]benzene

  • CAS：2712-78-9
  • purity：99%
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1.What is the [Bis(trifluoroacetoxy)iodo]benzene ?

[Bis(trifluoroacetoxy)iodo]benzene acts as a reagent in Pummerer-like reactions. It plays an important role in the direct alfa-hydroxylation of ketones under acidic conditions. It is involved in the cyclization of styryl amines to N-alkyl or N-aryl indoles. It serves as a reagent for the chemoselective deprotection of dimethoxybenzyl ethers and tosyloxylation of anilides. Further, it is used in the synthesis of 1,3,4-oxadiazoles by the oxidation of N-acylhydrazones. In addition to this, it is employed in the Hofmann rearrangement for the conversion of cyclobutanecarboxamide to cyclobutylamine hydrochloride.

iodobenzene
591-50-4

iodobenzene

trifluoroacetic anhydride
407-25-0

trifluoroacetic anhydride

p-nitrobenzene iodide
636-98-6

p-nitrobenzene iodide

μ-oxo<nitrato(phenyl)iodine><phenyl(trifluoroacetato)iodine>
118311-30-1

μ-oxo

bis-[(trifluoroacetoxy)iodo]benzene
2712-78-9

bis-[(trifluoroacetoxy)iodo]benzene

Conditions
Conditions Yield
With nitric acid; acetic anhydride; In dichloromethane; at -20 ℃; for 0.666667h;
2.5%
2 g
With nitric acid; acetic anhydride; In dichloromethane; at -20 ℃; for 0.666667h; Product distribution; variation of temperature, reagent, time;
2.5%
2 g
iodobenzene
591-50-4

iodobenzene

iodopentafluorobenzene bis(trifluoroacetate)
14353-88-9

iodopentafluorobenzene bis(trifluoroacetate)

1,2,3,4,5-pentafluoro-6-iodobenzene
827-15-6

1,2,3,4,5-pentafluoro-6-iodobenzene

bis-[(trifluoroacetoxy)iodo]benzene
2712-78-9

bis-[(trifluoroacetoxy)iodo]benzene

Conditions
Conditions Yield
With dimethylsulfoxide-d6; at 20 ℃; for 1.58333h; Inert atmosphere;

2.What is the CAS number for [Bis(trifluoroacetoxy)iodo]benzene ?

The CAS number of [Bis(trifluoroacetoxy)iodo]benzene is 2712-78-9.

More information of [Bis(trifluoroacetoxy)iodo]benzene 2712-78-9 are:

CAS?Number

 2712-78-9

Density

 1.95g/cm3

Melting Point

 121-125 °C(lit.)

Boiling Point

 267.573oC at 760 mmHg

Flash Point

 115.624oC

Vapor Pressure

 0.008mmHg at 25°C

Refractive Index

 1.483

HS CODE

 29036990

PSA

 52.60000

LogP

 3.40360

3.What are another words for [Bis(trifluoroacetoxy)iodo]benzene ?

Synonyms?for?[Bis(trifluoroacetoxy)iodo]benzene 2712-78-9:Iodine, phenylbis(trifluoroacetato-kO)- (9CI);BTIB;Bis(trifluoroacetoxy)iodobenzene;Iodobenzene bis(trifluoroacetate);PIFA;Phenyliodine bis(trifluoroacetate);Iodine,phenylbis(2,2,2-trifluoroacetato-kO)-;

4.What is the molecular formula of [Bis(trifluoroacetoxy)iodo]benzene?

The chemical formula of ?[Bis(trifluoroacetoxy)iodo]benzene is?C10H5F6IO4 which containing 10 Carbon atoms,5 Hydrogen atoms,6 Fluorine atoms,1 Iodine atoms and 4 Oxygen atoms,and the molecular weight of??[Bis(trifluoroacetoxy)iodo]benzene?is 430.042.

5.What is [Bis(trifluoroacetoxy)iodo]benzene (2712-78-9) used for?

[Bis(trifluoroacetoxy)iodo]benzene is a white to pale yellow crystalline powder that is widely utilized in various chemical reactions due to its unique properties. It is known for its ability to act as a reagent in a range of processes, including oxidation, cyclization, dehydrogenation, and dearomatization reactions.

InChI:InChI=1/C10H3F6IO4/c11-9(12,13)7(18)20-5-3-1-2-4(17)6(5)21-8(19)10(14,15)16/h1-3H

Relevant articles related to [Bis(trifluoroacetoxy)iodo]benzene:

Article

Source

Synthesis of Aryl(2,4,6-trimethoxyphenyl)iodonium Trifluoroacetate Salts

Carreras, Virginie,Sandtorv, Alexander H.,Stuart, David R.

, p. 1279 - 1284 (2017)

STUDIES AIMING AT THE SYNTHESIS OF MORPHINE II. Studies on Phenolic Coupling of N-Norreticuline Derivates

Szantay, Csaba,Blasko, Gabor,Barczai-Beke, Marietta,Pechy, Peter,Dornyei, Gabor

, p. 3509 - 3512 (1980)

6.Buy [Bis(trifluoroacetoxy)iodo]benzene with the best price .

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