Details
Quality manufacturer supply DIETHYL PHOSPHATE 598-02-7 in stock with high standard
- Molecular Formula:C4H11 O4 P
- Molecular Weight:154.103
- Vapor Pressure:0.137mmHg at 25°C
- Melting Point:6 °C
- Refractive Index:1.4170
- Boiling Point:203 °C
- PKA:1.42±0.50(Predicted)
- Flash Point:74.9°C
- PSA：65.57000
- Density:1.195g/cm3
- LogP:1.15980
DIETHYL PHOSPHATE(Cas 598-02-7) Usage
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Synthesis Reference(s) |
The Journal of Organic Chemistry, 28, p. 2089, 1963 DOI: 10.1021/jo01043a035Tetrahedron Letters, 29, p. 619, 1988 DOI: 10.1016/S0040-4039(00)80165-3 |
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Definition |
ChEBI: A dialkyl phosphate having ethyl as the alkyl group. |
InChI:InChI=1/C4H11O4P/c1-3-7-9(5,6)8-4-2/h3-4H2,1-2H3,(H,5,6)/p-1
598-02-7 Relevant articles
Rhodium-catalyzed phosphorylation reaction of water-soluble disulfides using hypodiphosphoric acid tetraalkyl esters in water
Arisawa, Mieko,Fukumoto, Kohei,Yamaguchi, Masahiko
, p. 13820 - 13823 (2020)
RhCl3 catalyzed the exchange reaction of...
Ionization of the PH Bond in Diethyl Phosphonate
Lewis, Edward S.,Spears, L. Gene
, p. 3918 - 3921 (1985)
Diethyl phosphonate is oxidized by halog...
Diethyl Isopropyl and Isopropenyl Phosphate via Differently Generated Ketyl Radicals of Acetone Reacting with Diethyl Phosphoric Acid
Schole, Juergen,Schole, Christine,Eikemeyer, Juergen,Krebs, Hans Christoph
, p. 1125 - 1128 (1994)
Photochemically excited acetone reacts i...
Synthesis and structure of complexes of phosphorus pentachloride with 4-dimethylaminopyridine and n-methylimidazole
Pipko, Sergey E.,Bezgubenko, Ludmila V.,Sinitsa, Anatoliy D.,Rusanov, Eduard B.,Kapustin, Evgeniy G.,Povolotskii, Mark I.,Shvadchak, Volodymyr V.
, p. 171 - 177 (2008)
Complexes of phosphorus pentachloride wi...
Wireless Hazard Badges to Detect Nerve-Agent Simulants
Zhu, Rong,Azzarelli, Joseph M.,Swager, Timothy M.
, p. 9662 - 9666 (2016)
Human exposure to hazardous chemicals ca...
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Mukaiyama,Fujisawa
, p. 812 (1961)
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Broad-Spectrum Liquid- and Gas-Phase Decontamination of Chemical Warfare Agents by One-Dimensional Heteropolyniobates
Guo, Weiwei,Lv, Hongjin,Sullivan, Kevin P.,Gordon, Wesley O.,Balboa, Alex,Wagner, George W.,Musaev, Djamaladdin G.,Bacsa, John,Hill, Craig L.
, p. 7403 - 7407 (2016)
A wide range of chemical warfare agents ...
Prodrugs of butyric acid. Novel derivatives possessing increased aqueous solubility and potential for treating cancer and blood diseases
Nudelman, Abraham,Gnizi, Elisheva,Katz, Yifat,Azulai, Revital,Cohen-Ohana, Mirit,Zhuk, Regina,Sampson, Sanford R,Langzam, Leah,Fibach, Eitan,Prus, Eugenia,Pugach, Victoria,Rephaeli, Ada
, p. 63 - 74 (2001)
The synthesis and biological activities ...
Does phosphoryl protonation occurs in aqueous phosphoesters solutions
Azema,Ladame,Lapeyre,Zwick,Lakhdar-Ghazal
, p. 287 - 292 (2005)
Ionisation of trimethylphosphate (TMP), ...
Effect of the molecular size of analytes on polydicetylene chromism
Seo, Donghwan,Kim, Jinsang
, p. 1397 - 1403 (2010)
The pH chromism of polydiacetylenes (PDA...
Kinetic and isotope effect studies on the intermediacy of ethyl metathiophosphate in ethanolysis of O-ethyl N-1-adamantyl phosphoramidothioate
Jankowski, Stefan,Quin, Louis D.,Paneth, Piotr,O'Leary, Marion H.
, p. 23 - 27 (1997)
The fragmentation of O-ethyl N-l-adamant...
MIL-101(Cr) with incorporated polypyridine zinc complexes for efficient degradation of a nerve agent simulant: spatial isolation of active sites promoting catalysis
Zhang, Kai,Cao, Xingyun,Zhang, Zhiyan,Cheng, Yong,Zhou, Ying-Hua
supporting information, p. 1995 - 2000 (2021/02/26)
Development of an efficient catalyst for...
Paraoxonase Mimic by a Nanoreactor Aggregate Containing Benzimidazolium Calix and l-Histidine: Demonstration of the Acetylcholine Esterase Activity
Singh, Amanpreet,Saini, Sanjeev,Mayank,Kaur, Navneet,Singh, Ajnesh,Singh, Narinder,Jang, Doo Ok
, p. 5737 - 5744 (2021/03/08)
An anion-mediated preorganization approa...
METHOD FOR PRODUCING PHOSPHOESTER COMPOUND
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Paragraph 0023-0025, (2021/09/27)
PROBLEM TO BE SOLVED: To provide a metho...
Organic-inorganic hybrid thorium polyacid salt and preparation method and application thereof
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Paragraph 0027, 0028, (2020/07/21)
The invention discloses an organic-inorg...
598-02-7 Process route
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311-45-5
paraoxon
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100-02-7,78813-13-5,89830-32-0
4-nitro-phenol
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598-02-7
Diethyl phosphate
| Conditions | Yield |
|---|---|
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With
tetraethylammonium hydroxide;
In
water; acetonitrile;
at 20 ℃;
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With
bacterial phosphotriesterase from Pseudomonas diminuta; n-Butylethynyl diethyl phosphate; 2,2'-piperazine-1,4-diyl-bis-ethanesulfonic acid;
In
water; acetonitrile;
at 25 ℃;
Rate constant;
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With
tetraethylammonium hydroxide;
In
water; acetonitrile;
at 20 ℃;
Rate constant;
Variation of the velocity constant with various concentration of water.;
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With
sodium hydroxide;
In
water;
for 0.5h;
Thermodynamic data;
Kinetics;
Rate constant;
Heating;
other temperatures, activation energy;
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With
TAPS buffer; sodium perchlorate;
2-Et2NCH2-6-<(HOCH2CH2)MeNCH2>py-Zn(II);
In
water;
at 50 ℃;
for 1h;
Rate constant;
var. pH, temp., catalyst;
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With
organophosphorus acid anhydrolase from Alteromonas sp. JD6.5; water;
at 25 ℃;
Enzyme kinetics;
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With
organophosphorus hydrolase from Pseudomonas sp;
In
phosphate buffer;
at 25 ℃;
pH=8.0;
Enzyme kinetics;
Equilibrium constant;
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With
sodium perchlorate;
cycloplatinated aryl ketoxime;
In
acetonitrile;
at 25 ℃;
pH=8.5;
Further Variations:;
pH-values;
Kinetics;
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With
iron(III) oxide; phosphate buffer; Nα-α-aspartyl-histidine;
at 40 ℃;
pH=7.4;
Kinetics;
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With
water;
cobalt(II);
pH=7.3;
Enzyme kinetics;
|
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With
potassium chloride; bis(N,N-dimethylacetamide)hydrogen dibromobromate;
In
water;
at 25 ℃;
pH=11.35;
Reagent/catalyst;
pH-value;
Kinetics;
|
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With
water;
Fe2O3-Asp-His nanocomplex;
at 37 ℃;
for 96h;
pH=7;
Conversion of starting material;
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With
copolymerized N,N-methylenebisacrylamide and N-methacryloyl-histidine-Cu2+ complex on polystyrene microspheres;
at 25 ℃;
pH=9;
Reagent/catalyst;
Kinetics;
aq. buffer;
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With
sodium phosphate;
In
aq. phosphate buffer; water; dimethyl sulfoxide;
at 25 ℃;
for 0.333333h;
pH=7.5;
Enzymatic reaction;
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With
phosphotriesterase like lactonases from Deinococcus radiodurans; water; cobalt(II) chloride;
at 30 ℃;
pH=9;
Reagent/catalyst;
Kinetics;
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With
2-hydroxyiminomethyl-1-methylpyridinium chloride;
In
aq. phosphate buffer; acetonitrile;
at 20 ℃;
pH=7.4;
pH-value;
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With
4-methyl-morpholine;
In
water;
at 45 ℃;
for 24h;
pH=10;
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With
5-(hydroxyamino)-5-oxopentanoic acid;
In
aq. phosphate buffer;
at 37 ℃;
for 24h;
pH=10.5;
Reagent/catalyst;
pH-value;
Temperature;
Kinetics;
Catalytic behavior;
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With
MIL-101(Cr)(4′-(4-pyridyl)-2,2′:6′,2″-terpyridine)Zn;
In
methanol;
at 39.84 ℃;
pH=10;
pH-value;
Kinetics;
Activation energy;
|
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With
2HO(1-)*C36H38N4(2+);
Kinetics;
Catalytic behavior;
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113680-16-3
diethyl (2-(4-methoxyphenyl)-2-oxoethyl) phosphate
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598-02-7
Diethyl phosphate
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100-06-1
1-(4-methoxyphenyl)ethanone
| Conditions | Yield |
|---|---|
|
With
1,4-dioxane; triethylamine;
at -20 ℃;
for 8h;
Mechanism;
Product distribution;
Irradiation;
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84% 86% |
598-02-7 Upstream products
-
109-02-4
4-methyl-morpholine
-
78-40-0
triethyl phosphate
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141-52-6
sodium ethanolate
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1186-09-0
O,O,S-triethyl phosphorothioate
598-02-7 Downstream products
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107-49-3
Tetraethyl pyrophosphate
-
645-78-3
tetraethyl thiopyrophosphate
-
3689-24-5
sulfotep
-
78-40-0
triethyl phosphate
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